文章基本信息

标题：Modeling of nitrate removal from aqueous solution by Fe-doped TiO2 under UV and solar irradiation using response surface methodology
本地全文：下载
作者：Zazouli M.A ; Safarpour M ; Dobaradaran S. 等
期刊名称：Global Nest
印刷版ISSN：1790-7632
电子版ISSN：2241-777X
出版年度：2015
卷号：17
期号：2
页码：379-388
DOI：10.30955/gnj.001577
出版社：Global Nest
摘要：Nitrate is a common groundwater pollutant all over the world. In some regions of Iran, its levels are high enough to cause serious problems to human health and the environment . The objectives of this work were to evaluate the efficiency of Fe-doped TiO₂ nanoparticles at removing nitrate from aqueous solutions under UV and solar radiation and to model nitrate removal using response surface methodology techniques. In this study, a response surface methodology based on the Box–Behnken design matrix was used to describe the process of nitrate removal from an aqueous solution with four independent parameters, namely Fe-doped TiO₂ (dose 1-2 g l^-1), nitrate concentration (25-100 mg l^-1), contact time (10-120 min), and pH (4-9). The results indicated that the removal efficiency of nitrate in the presence of ultraviolet and solar radiation was 56.5 % and 21.8%, respectively. The removal efficiency of nitrate increased with time and initial concentration of nitrate. Analysis of variance (ANOVA) indicated that the proposed model was essentially in accordance with the experimental results with the correlation coefficient R²= 0.9237 and Adj-R² = 0.8347. Response surface methodology (RSM) proved to be a powerful statistical tool for investigating the operating conditions for nitrate removal under UV irradiation.
关键词：Box–Behnken design; nitrate; response surface methodology; ultraviolet light; nano Fe-doped TiO2